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Fluoride half cell lon selective electrode hanna hi4010
The HI4010 fluoride selective electrode is a potentiometric half-cell that housed within an epoxy body. The internal elements are isolated from the sample by a lanthanum fluoride crystal membrane. This solid state sensor requires a separate reference electrode to complete the measurement system.
For the HI4010 to accurately measure total fluoride concentration, it is important that the pH and ionic strength of the standards and sample be adjusted to a constant value. The total ionic strength adjustment buffer (TISAB) ensures that the solution pH is between pH 5 and 8 and that the activity coefficient is constant. The TISAB solution also preferentially complexes with various metal ions, such as aluminum and iron, which tend to form complexes with fluoride ions. TISAB thus ensures that these metal ions do not interfere, permitting an accurate total fluoride measurement. Measuring all solutions with a constant pH and ionic strength reduces the margin of error between measurements. The HI4010 fluoride solid state ISE can measure from 1µM (0.02 mg/L) to saturated F-.
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